̽��ֱ�� of Cambridge - Rohit Chikkaraddy

Colour-changing magnifying glass gives clear view of infrared light

sc604 — Thu, 02 Dec 2021 19:00:00 +0000

Detecting light beyond the visible red range of our eyes is hard to do, because infrared light carries so little energy compared to ambient heat at room temperature. This obscures infrared light unless specialised detectors are chilled to very low temperatures, which is both expensive and energy-intensive.

Now researchers led by the ̽��ֱ�� of Cambridge have demonstrated a new concept in detecting infrared light, showing how to convert it into visible light, which is easily detected.

In collaboration with colleagues from the UK, Spain and Belgium, the team used a single layer of molecules to absorb the mid-infrared light inside their vibrating chemical bonds. These shaking molecules can donate their energy to visible light that they encounter, ‘upconverting’ it to emissions closer to the blue end of the spectrum, which can then be detected by modern visible-light cameras.

̽��ֱ��results, reported in the journal Science, open up new low-cost ways to sense contaminants, track cancers, check gas mixtures, and remotely sense the outer universe.

̽��ֱ��challenge faced by the researchers was to make sure the quaking molecules met the visible light quickly enough. “This meant we had to trap light really tightly around the molecules, by squeezing it into crevices surrounded by gold,” said first author Angelos Xomalis from Cambridge’s Cavendish Laboratory.

̽��ֱ��researchers devised a way to sandwich single molecular layers between a mirror and tiny chunks of gold, only possible with ‘meta-materials’ that can twist and squeeze light into volumes a billion times smaller than a human hair.

“Trapping these different colours of light at the same time was hard, but we wanted to find a way that wouldn’t be expensive and could easily produce practical devices,” said co-author Dr Rohit Chikkaraddy from the Cavendish Laboratory, who devised the experiments based on his simulations of light in these building blocks.

“It’s like listening to slow-rippling earthquake waves by colliding them with a violin string to get a high whistle that’s easy to hear, and without breaking the violin,” said Professor Jeremy Baumberg of the NanoPhotonics Centre at Cambridge’s Cavendish Laboratory, who led the research.

̽��ֱ��researchers emphasise that while it is early days, there are many ways to optimise the performance of these inexpensive molecular detectors, which then can access rich information in this window of the spectrum.

From astronomical observations of galactic structures to sensing human hormones or early signs of invasive cancers, many technologies can benefit from this new detector advance.

̽��ֱ��research was conducted by a team from the ̽��ֱ�� of Cambridge, KU Leuven, ̽��ֱ�� College London (UCL), the Faraday Institution, and Universitat Politècnica de València.

̽��ֱ��research is funded as part of a UK Engineering and Physical Sciences Research Council (EPSRC) investment in the Cambridge NanoPhotonics Centre, as well as the European Research Council (ERC), Trinity College Cambridge and KU Leuven.

Jeremy Baumberg is a Fellow of Jesus College, Cambridge.

Reference:
Angelos Xomalis et al. ‘Detecting mid-infrared light by molecular frequency upconversion with dual-wavelength hybrid nanoantennas’, Science (2021). DOI: 10.1126/science.abk2593

By trapping light into tiny crevices of gold, researchers have coaxed molecules to convert invisible infrared into visible light, creating new low-cost detectors for sensing.

It’s like listening to slow-rippling earthquake waves by colliding them with a violin string to get a high whistle that’s easy to hear, and without breaking the violin

Jeremy Baumberg

NanoPhotonics Cambridge /Ermanno Miele, Jeremy Baumberg

Nano-antennas convert invisible infrared into visible light

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Nano ‘hall of mirrors’ causes molecules to mix with light

sc604 — Mon, 13 Jun 2016 15:00:00 +0000

When a molecule emits a blink of light, it doesn’t expect it to ever come back. However researchers have now managed to place single molecules in such a tiny optical cavity that emitted photons, or particles of light, return to the molecule before they have properly left. ̽��ֱ��energy oscillates back and forth between light and molecule, resulting in a complete mixing of the two.

Previous attempts to mix molecules with light have been complex to produce and only achievable at very low temperatures, but the researchers, led by the ̽��ֱ�� of Cambridge, have developed a method to produce these ‘half-light’ molecules at room temperature.

These unusual interactions of molecules with light provide new ways to manipulate the physical and chemical properties of matter, and could be used to process quantum information, aid in the understanding of complex processes at work in photosynthesis, or even manipulate the chemical bonds between atoms. ̽��ֱ��results are reported in the journal Nature.

To use single molecules in this way, the researchers had to reliably construct cavities only a billionth of a metre (one nanometre) across in order to trap light. They used the tiny gap between a gold nanoparticle and a mirror, and placed a coloured dye molecule inside.

“It’s like a hall of mirrors for a molecule, only spaced a hundred thousand times thinner than a human hair,” said Professor Jeremy Baumberg of the NanoPhotonics Centre at Cambridge’s Cavendish Laboratory, who led the research.

In order to achieve the molecule-light mixing, the dye molecules needed to be correctly positioned in the tiny gap. “Our molecules like to lie down flat on the gold, and it was really hard to persuade them to stand up straight,” said Rohit Chikkaraddy, lead author of the study.

To solve this, the team joined with a team of chemists at Cambridge led by Professor Oren Scherman to encapsulate the dyes in hollow barrel-shaped molecular cages called cucurbiturils, which are able to hold the dye molecules in the desired upright position.

When assembled together correctly, the molecule scattering spectrum splits into two separated quantum states which is the signature of this ‘mixing’. This spacing in colour corresponds to photons taking less than a trillionth of a second to come back to the molecule.

A key advance was to show strong mixing of light and matter was possible for single molecules even with large absorption of light in the metal and at room temperature. “Finding single-molecule signatures took months of data collection,” said Chikkaraddy.

̽��ֱ��researchers were also able to observe steps in the colour spacing of the states corresponding to whether one, two, or three molecules were in the gap.

̽��ֱ��Cambridge team collaborated with theorists Professor Ortwin Hess at the Blackett Laboratory, Imperial College London and Dr Edina Rosta at Kings College London to understand the confinement and interaction of light in such tiny gaps, matching experiments amazingly well.

Reference:
Rohit Chikkaraddy et al. ‘Single-molecule strong coupling at room temperature in plasmonic nanocavities.’ Nature (2016). DOI: 10.1038/nature17974

Researchers have successfully used quantum states to mix a molecule with light at room temperature, which will aid in the exploration of quantum technologies and provide new ways to manipulate the physical and chemical properties of matter.

It’s like a hall of mirrors for a molecule, only spaced a hundred thousand times thinner than a human hair.

Jeremy Baumberg

Yu Ji/ ̽��ֱ�� of Cambridge NanoPhotonics

Mixing light with dye molecules, trapped in golden gaps

̽��ֱ��text in this work is licensed under a Creative Commons Attribution 4.0 International License. For image use please see separate credits above.

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