̽��ֱ�� of Cambridge - Ventsislav Valev

Building ‘invisible’ materials with light

sc604 — Mon, 28 Jul 2014 09:00:00 +0000

A new method of building materials using light, developed by researchers at the ̽��ֱ�� of Cambridge, could one day enable technologies that are often considered the realm of science fiction, such as invisibility cloaks and cloaking devices.

Although cloaked starships won’t be a reality for quite some time, the technique which researchers have developed for constructing materials with building blocks a few billionths of a metre across can be used to control the way that light flies through them, and works on large chunks all at once. Details are published today (28 July) in the journal Nature Communications.

̽��ֱ��key to any sort of ‘invisibility’ effect lies in the way light interacts with a material. When light hits a surface, it is either absorbed or reflected, which is what enables us to see objects. However, by engineering materials at the nanoscale, it is possible to produce ‘metamaterials’: materials which can control the way in which light interacts with them. Light reflected by a metamaterial is refracted in the ‘wrong’ way, potentially rendering objects invisible, or making them appear as something else.

Metamaterials have a wide range of potential applications, including sensing and improving military stealth technology. However, before cloaking devices can become reality on a larger scale, researchers must determine how to make the right materials at the nanoscale, and using light is now shown to be an enormous help in such nano-construction.

̽��ֱ��technique developed by the Cambridge team involves using unfocused laser light as billions of needles, stitching gold nanoparticles together into long strings, directly in water for the first time. These strings can then be stacked into layers one on top of the other, similar to Lego bricks. ̽��ֱ��method makes it possible to produce materials in much higher quantities than can be made through current techniques.

In order to make the strings, the researchers first used barrel-shaped molecules called cucurbiturils (CBs). ̽��ֱ��CBs act like miniature spacers, enabling a very high degree of control over the spacing between the nanoparticles, locking them in place.

In order to connect them electrically, the researchers needed to build a bridge between the nanoparticles. Conventional welding techniques would not be effective, as they cause the particles to melt. “It’s about finding a way to control that bridge between the nanoparticles,” said Dr Ventsislav Valev of the ̽��ֱ��’s Cavendish Laboratory, one of the authors of the paper. “Joining a few nanoparticles together is fine, but scaling that up is challenging.”

̽��ֱ��key to controlling the bridges lies in the cucurbiturils: the precise spacing between the nanoparticles allows much more control over the process. When the laser is focused on the strings of particles in their CB scaffolds, it produces plasmons: ripples of electrons at the surfaces of conducting metals. These skipping electrons concentrate the light energy on atoms at the surface and join them to form bridges between the nanoparticles. Using ultrafast lasers results in billions of these bridges forming in rapid succession, threading the nanoparticles into long strings, which can be monitored in real time.

“We have controlled the dimensions in a way that hasn’t been possible before,” said Dr Valev, who worked with researchers from the Department of Chemistry, the Department of Materials Science & Metallurgy, and the Donostia International Physics Center in Spain on the project. “This level of control opens up a wide range of potential practical applications.”

A new technique which uses light like a needle to thread long chains of particles could help bring sci-fi concepts such as cloaking devices one step closer to reality.

This level of control opens up a wide range of potential practical applications

Ventsislav Valev

An efficient route to manufacturing nanomaterials with light through plasmon-induced laser-threading of gold nanoparticle strings

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Yes

Exposing ‘evil twins’

sc604 — Fri, 16 May 2014 07:23:08 +0000

A direct relationship between the way in which light is twisted by nanoscale structures and the nonlinear way in which it interacts with matter could be used to ensure greater purity for pharmaceuticals, allowing for ‘evil twins’ of drugs to be identified with much greater sensitivity.

Researchers from the ̽��ֱ�� of Cambridge have used this relationship, in combination with powerful lasers and nanopatterned gold surfaces, to propose a sensing mechanism that could be used to identify the right-handed and left-handed versions of molecules.

Some molecules are symmetrical, so their mirror image is an exact copy. However, most molecules in nature have a mirror image that differs - try putting a left-handed glove on to your right hand and you’ll see that your hands are not transposable one onto the other. Molecules whose mirror-images display this sort of “handedness” are known as chiral.

̽��ֱ��chirality of a molecule affects how it interacts with its surroundings, and different chiral forms of the same molecule can have completely different effects. Perhaps the best-known instance of this is Thalidomide, which was prescribed to pregnant women in the 1950s and 1960s. One chiral form of Thalidomide worked as an effective treatment for morning sickness in early pregnancy, while the other form, like an ‘evil twin’, prevented proper growth of the foetus. ̽��ֱ��drug that was prescribed to patients however, was a mix of both forms, resulting in more than 10,000 children worldwide being born with serious birth defects, such as shortened or missing limbs.

When developing new pharmaceuticals, identifying the correct chiral form is crucial. Specific molecules bind to specific receptors, so ensuring the correct chiral form is present determines the purity and effectiveness of the end product. However, the difficulty with achieving chiral purity is that usually both forms are synthesised in equal quantities.

Researchers from the ̽��ֱ�� of Cambridge have designed a new type of sensing mechanism, combining a unique twisting property of light with frequency doubling to identify different chiral forms of molecules with extremely high sensitivity, which could be useful in the development of new drugs. ̽��ֱ��results are published in the journal Advanced Materials.

̽��ֱ��sensing mechanism, designed by Dr Ventsislav Valev and Professor Jeremy Baumberg from the Cavendish Laboratory, in collaboration with colleagues from the UK and abroad, uses a nanopatterned gold surface in combination with powerful lasers.

Currently, differing chiral forms of molecules are detected by using beams of polarised light. ̽��ֱ��way in which the light is twisted by the molecules results in chiroptical effects, which are typically very weak. By using powerful lasers however, second harmonic generation (SHG) chiroptical effects emerge, which are typically three orders of magnitude stronger. SHG is a quantum mechanical process whereby two red photons can be annihilated to create a blue photon, creating blue light from red.

Recently, another major step towards increasing chiroptical effects came from the development of superchiral light – a super twisty form of light.

̽��ֱ��researchers identified a direct link between the fundamental equations for superchiral light and SHG, which would make even stronger chiroptical effects possible. Combining superchiral light and SHG could yield record-breaking effects, which would result in very high sensitivity for measuring the chiral purity of drugs.

̽��ֱ��researchers also used tiny gold structures, known as plasmonic nanostructures, to focus the beams of light. Just as a glass lens can be used to focus sunlight to a certain spot, these plasmonic nanostructures concentrate incoming light into hotspots on their surface, where the optical fields become huge. Due to the presence of optical field variations, it is in these hotspots that superchiral light and SHG combine their effects.

“By using nanostructures, lasers and this unique twisting property of light, we could selectively destroy the unwanted form of the molecule, while leaving the desired form unaffected,” said Dr Valev. “Together, these technologies could help ensure that new drugs are safe and pure.”

A combination of nanotechnology and a unique twisting property of light could lead to new methods for ensuring the purity and safety of pharmaceuticals.

Together, these technologies could help ensure that new drugs are safe and pure

Ventsislav Valev

When twisted light matches the twist of nanostructures, strong interactions with chiral molecules could arise

Yes